We report a measurement of the radium ion’s 7p 2Po3/2 state branching fractions and improved theoretical calculations. With a single laser-cooled radium-226 ion we measure the P3/2 branching fractions to the 7s 2S1/2 ground state 0.87678(20), the 6d 2D5/2 state 0.10759(10), and the 6d 2D3/2 state 0.01563(21).